Robert Sanderson Mulliken was an American physicist and chemist who received the Nobel Prize for Chemistry in 1966 for his work on the structure of molecules
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Robert Sanderson Mulliken was an American physicist and chemist who received the Nobel Prize for Chemistry in 1966 for his work on the structure of molecules
Robert S. Mulliken born at
Robert Mulliken was born in Newburyport, Massachusetts on June 7, 1896 to Samuel Parsons Mulliken and Katherine W. Mulliken. Samuel Mulliken was a professor of Organic Chemistry at the Massachusetts Institute of Technology (MIT).
He assisted his father in editorial work of his four volume text book on ‘Organic Compound Identification’ and eventually became a master of the nomenclature of organic chemistry.
As a child, Mulliken had a brilliant as well as a selective memory. For instance, he mastered the botanical name of plants, but couldn’t remember his most favorite German high school teacher.
Mulliken graduated from school in 1913 and received a scholarship to join the MIT which his father had also received, during his education. Like his father, he also took up majors in chemistry. He received his B.S degree in chemistry from MIT in 1917.
In 1917, the United States had just entered the World War I and Mulliken got a wartime job as a Junior Chemical Engineer and worked for the United States Bureau of Mines. He also conducted research on poisonous gases at the American University, Washington D.C at that time.
After World War I ended in 1918, Mulliken worked as a Chemist at the New Jersey Zinc Company for a year.
He realized that it was not what he wanted to do and quit the job to pursue a PhD at the University of Chicago in 1919.
He obtained his doctorate in 1921 for his research on separation of isotopes of the molecules of Mercury by evaporation. He continued with his isotope research until he attended a course conducted by Nobel laureate physicist Robert A. Millikan, which kick started his interest in Quantum theory.
In 1925, Mulliken travelled to Europe and worked on Quantum Mechanics with outstanding scientists of the time such as Erwin Schrodinger, Max Born, Werner Heisenberg and others for the next two years.
In 1927, Mulliken worked with Friedrich Hund and developed the Hund-Mulliken theory.
He was also responsible for developing the ‘Mulliken Population Analysis’, a method of assigning charges to atoms in a molecule.
In 1934, he devised a method for estimating the electro negativity of elements. It was not as popular as Pauling electro negativity which can be found in textbooks, but considered to be a better indicator of the electro negativity property by experts.
During the World War II (from 1942 to 1945), he collaborated in the Manhattan project and was appointed as the Director of Information Division for the Plutonium Project at the University of Chicago.